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File://t:\lab\wpdocs\admnasst\product information\msds's update

WATTYL GRANOSITE GRANOTROWL
Chemwatch Material Safety Data Sheet
CHEMWATCH 19714
Issue Date: 16-Mar-2007
Version No:4
NC317ECP
Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME
SYNONYMS
PRODUCT USE
Applied using a hand trowel or spreader. High- build acrylic texture coating system. SUPPLIER
Section 2 - HAZARDS IDENTIFICATION
STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to the Criteria of
NOHSC, and the ADG Code.
POISONS SCHEDULE
Do not breathe gas/ fumes/ vapour/ spray. Limited evidence of a carcinogenic effect. Harmful: danger of serious damage to health by prolonged exposure through inhalation. Wear suitable protective clothing. Use only in wel ventilated areas. Keep container in a wel ventilated place. To clean the floor and al objects contaminated by this Keep away from food drink and animal feeding stuffs. Take off immediately al contaminated clothing. In case of contact with eyes rinse with plenty of water and contact Doctor or Poisons Information Centre. If swal owed IMMEDIATELY contact Doctor or Poisons Information Centre (show this container or label). Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS
file://T:\Lab\WPDOCS\ADMNASST\Product Information\MSDS's Updated\Updates . 11/01/2008 Section 4 - FIRST AID MEASURES
SWALLOWED
· First aid is not general y required. If in doubt, contact a Poisons Information Centre If this product comes in contact with the eyes: · Wash out immediately with fresh running water. · Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasional y lifting the upper and lower lids. · If pain persists or recurs seek medical attention. · Removal of contact lenses after an eye injury should only be undertaken by skil ed · Immediately remove al contaminated clothing, including footwear. · Flush skin and hair with running water (and soap if available). · Seek medical attention in event of irritation. INHALED · If fumes or combustion products are inhaled remove from contaminated area.
· Lay patient down. Keep warm and rested. · Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures. · Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary. NOTES TO PHYSICIAN
Section 5 - FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA
· There is no restriction on the type of extinguisher which may be used. · Use extinguishing media suitable for surrounding area. FIRE FIGHTING
· Alert Fire Brigade and tel them location and nature of hazard. · Wear breathing apparatus plus protective gloves for fire only. · Prevent, by any means available, spil age from entering drains or water courses. · Use fire fighting procedures suitable for surrounding area. · DO NOT approach containers suspected to be hot. · Cool fire exposed containers with water spray from a protected location. · If safe to do so, remove containers from path of fire. · Equipment should be thoroughly decontaminated after use. FIRE/EXPLOSION HAZARD
· The material is not readily combustible under normal conditions. · However, it wil break down under fire conditions and the organic component may burn. · Not considered to be a significant fire risk. · Heat may cause expansion or decomposition with violent rupture of containers. · Decomposes on heating and may produce toxic fumes of carbon monoxide (CO). file://T:\Lab\WPDOCS\ADMNASST\Product Information\MSDS's Updated\Updates . 11/01/2008 FIRE INCOMPATIBILITY
HAZCHEM: None
Section 6 - ACCIDENTAL RELEASE MEASURES
EMERGENCY PROCEDURES
MINOR SPILLS
· Avoid breathing vapours and contact with skin and eyes. · Control personal contact by using protective equipment. · Contain and absorb spil with sand, earth, inert material or vermiculite. · Place in a suitable label ed container for waste disposal. MAJOR SPILLS
· Alert Fire Brigade and tel them location and nature of hazard. · Control personal contact by using protective equipment as required. · Prevent spil age from entering drains or water ways. · Contain spil with sand, earth or vermiculite. · Col ect recoverable product into label ed containers for recycling. · Absorb remaining product with sand, earth or vermiculite and place in appropriate · Wash area and prevent runoff into drains or waterways. · If contamination of drains or waterways occurs, advise emergency services. EMERGENCY RESPONSE PLANNING GUIDELINES (ERPG)
The maximum airborne concentration below which it is believed that nearly al individuals could be exposed for up to one hour WITHOUT experiencing or developing irreversible or other serious effects or symptoms which could impair an individual's ability to take silica crystal ine - quartz 0.25 mg/m³ other than mild, transient adverse effects without perceiving a clearly defined odour is: silica crystal ine - quartz 0.15 mg/m³ The threshold concentration below which most people wil experience no appreciable risk of health effects: silica crystal ine - quartz 0.15 mg/m³ American Industrial Hygiene Association (AIHA) Ingredients considered according to the fol owing cutoffs Very Toxic (T+) >= 0.1% Toxic (T) >= 3.0% R50 >= 0.25% Corrosive (C) >= 5.0% where percentage is percentage of ingredient found in the mixture Personal Protective Equipment advice is contained in Section 8 of the MSDS.
file://T:\Lab\WPDOCS\ADMNASST\Product Information\MSDS's Updated\Updates . 11/01/2008 Section 7 - HANDLING AND STORAGE
PROCEDURE FOR HANDLING
· Limit al unnecessary personal contact. · Wear protective clothing when risk of exposure occurs. · Avoid contact with incompatible materials. · When handling, DO NOT eat, drink or smoke. · Keep containers securely sealed when not in use. · Always wash hands with soap and water after handling. · Work clothes should be laundered separately. · Observe manufacturer's storing and handling recommendations. · Atmosphere should be regularly checked against established exposure standards to ensure SUITABLE CONTAINER
· Lined metal can, lined metal pail/ can. · Packing as recommended by manufacturer. · Check al containers are clearly label ed and free from leaks. STORAGE INCOMPATIBILITY
STORAGE REQUIREMENTS
· Store in a cool, dry, wel ventilated area. · Store away from incompatible materials. · Protect containers against physical damage and check regularly for leaks. · Observe manufacturer's storing and handling recommendations. Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE CONTROLS
file://T:\Lab\WPDOCS\ADMNASST\Product Information\MSDS's Updated\Updates . 11/01/2008 The fol owing materials had no OELs on our records EMERGENCY EXPOSURE LIMITS
MATERIAL DATA
Not available. Refer to individual constituents. INGREDIENT DATA
It is the goal of the ACGIH (and other Agencies) to recommend TLVs (or their equivalent) for al substances for which there is evidence of health effects at airborne concentrations encountered in the workplace. At this time no TLV has been established, even though this material may produce adverse health effects (as evidenced in animal experiments or clinical experience). Airborne concentrations must be maintained as low as is practical y possible and occupational exposure must be kept to a minimum. NOTE: The ACGIH occupational exposure standard for Particles Not Otherwise Specified Sensory irritants are chemicals that produce temporary and undesirable side-effects on the eyes, nose or throat. Historical y occupational exposure standards for these irritants have been based on observation of workers' responses to various airborne concentrations. Present day expectations require that nearly every individual should be protected against even minor sensory irritation and exposure standards are established using uncertainty factors or safety factors of 5 to 10 or more. On occasion animal no -observable-effect-levels (NOEL) are used to determine these limits where human results are unavailable. An additional approach, typical y used by the TLV committee (USA) in determining respiratory standards for this group of chemicals, has been to assign ceiling values (TLV C) to rapidly acting irritants and to assign short-term exposure limits (TLV STELs) when the weight of evidence from irritation, bioaccumulation and other endpoints combine to warrant such a limit. In contrast the MAK Commission (Germany) uses a five -category system based on intensive odour, local irritation, and elimination half-life. However this system is being replaced to be consistent with the European Union (EU) Scientific Committee for Occupational Exposure Limits (SCOEL); this is more closely OSHA (USA) concluded that exposure to sensory irritants can: · cause increased susceptibility to other irritants and infectious agents · lead to permanent injury or dysfunction · permit greater absorption of hazardous substances and · acclimate the worker to the irritant warning properties of these substances thus file://T:\Lab\WPDOCS\ADMNASST\Product Information\MSDS's Updated\Updates . 11/01/2008 No exposure limits set by NOHSC or ACGIH. The TLV-TWA is thought to be protective against the significant risk of physical irritation associated with exposure. Because the margin of safety of the quartz TLV is not known with certainty and given the associated link between silicosis and lung cancer it is recommended that quartz concentrations be maintained as far below the TLV WARNING: This substance has been classified by the IARC as Group 2B: Possibly Animal studies at 10 mg/m3 show no significant fibrosis, possibly reversible tissue reaction and the architecture of lung air spaces remains intact. Odour Threshold Value: Variously reported as 0.019 ppm and 55 ppm; NOTE: Detector tubes for ammonia, measuring in excess of 1 ppm, are The TLV-TWA is thought to be protective against irritation of the eyes and respiratory tract and minimise discomfort among workers that are not inured to its effects and systemic damage. Acclimatised persons are able to tolerate prolonged exposures of up to 100 ppm without symptoms. Marked irritation has been seen in persons exposed to ammonia concentrations between 50 and 100 ppm only when the exposures involved sudden concentration peaks which do not permit short-term acclimatisation. The detoxification capacity of the liver is significant since the amount of ammonia formed endogenously in the intestines markedly exceeds that from Human exposure effects, at vapour concentrations of about: -------------------------------------------------- -------------------------------------------------- 9-50 nasal dryness, olfactory fatigue and moderate irritation 125-137 definite nose, throat and chest irritation 500 30 minute exposures may produce cyclic hypernea, increased blood pressure and pulse rate, and upper respiratory tract irritation 1500-10000 dyspnea, convulsive coughing, chest pain, respiratory spasm, pink frothy sputum, rapid asphyxia and delayed pulmonary oedema which may be fatal. Other effects include runny nose, swel ing of the lips, restlessness, headache, salivation, nausea, vomiting, glottal oedema, pharyngitis, tracheitis, and speech difficulties. Bronchopneumonia, asphyxiation due to spasms, inflammation, and oedema of the larynx, may be fatal. Residual effects include hoarseness, productive cough, and decreased >2500 severe eye irritation, with swel ing of the eyelids, lachrymation, blepharospasm, palpebral oedema, increased intraocular pressure, oval semi-dilated, fixed pupils, corneal ulceration (often severe) and temporary blindness. Depending on duration of exposure, there may be destruction of the file://T:\Lab\WPDOCS\ADMNASST\Product Information\MSDS's Updated\Updates . 11/01/2008 epithelium, corneal and lenticular opacification, and iritis accompanied by hypopyon or haemorrhage and possible loss of pigment from the posterior layer of the iris. Less severe damage is often resolved. In the case of severe damage, symptoms may be delayed; late complications including persistent oedema, vascularisation and corneal scarring, permanent opacity, acute angle glaucoma, staphyloma, cataract, and atrophy of the retina, iris, and symblepharon. Long-term exposure to sub-acute concentrations or single exposures to high concentrations may produce chronic airway dysfunction, alveolar disease, bronchiolitis, bronchiectasis, emphysema and anxiety neuroses Exposed individuals are reasonably expected to be warned, by smel , that the Exposure Odour Safety Factor (OSF) is determined to fal into either Class A or B. The Odour Safety Factor (OSF) is defined as: OSF= Exposure Standard (TWA) ppm/ Odour Threshold Value (OTV) ppm persons being distracted10-50% of persons aware of Odour Threshold: 0.017 to 1.9 with a geometric average threshold of 0.32 ppm. NOTE:Detector tubes measuring styrene at greater than 10 ppm are available. The recommended TLV-TWA and STEL is based on the influence of styrene exposure on the central and peripheral nervous systems At the TWA, total daily styrene exposure to the standard 70 kg medium-frame man who inhales 10 m3 and who retains 70% of the inspired compound is 21 mg/kg with 0.5 mg/kg absorbed through the skin. The total absorbed dose can be increased six-fold with physical work and increased respiration rate. Measurement of styrene and its metabolites in the urine can be an indication of recent exposure though this approach may be limited by factors such as the influence of alcohol consumption on styrene pharmodynamics. Exposure at or below the TLV-TWA is thought to protect the worker against the significant risks of narcosis, neuropathies and irritation although other findings suggest that neuro-optical effects ar significant amongst workers exposed at 4 ppm. PERSONAL PROTECTION
EYE · Safety glasses with side shields; or as required,
· Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document, describing the wearing of lens or file://T:\Lab\WPDOCS\ADMNASST\Product Information\MSDS's Updated\Updates . 11/01/2008 restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly. [CDC NIOSH Current Intel igence Bul etin 59]. HANDS/FEET
Wear general protective gloves: i.e. Disposable polythene gloves or Cotton gloves or Light weight rubber gloves, with Barrier cream preferably Safety footwear. RESPIRATOR
Selection of the Class and Type of respirator wil depend upon the level of breathing zone contaminant and the chemical nature of the contaminant. Protection Factors (defined as the ratio of contaminant outside and inside the mask) may also be important. * - Continuous Flow ** - Continuous-flow or positive pressure demand. The local concentration of material, quantity and conditions of use determine the type of For further information consult site specific ENGINEERING CONTROLS
General exhaust is adequate under normal operating conditions. Local exhaust ventilation may be required in specific circumstances. If risk of overexposure exists, wear approved respirator. Correct fit is essential to obtain adequate protection. Provide adequate ventilation in warehouse or closed storage areas. Section 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE
Acrylic polymer emulsions may contain residual traces of odourous acrylic monomers; the amounts remaining in compounded mixtures represents a very low order of exposure, however file://T:\Lab\WPDOCS\ADMNASST\Product Information\MSDS's Updated\Updates . 11/01/2008 this may become noticeable with some materials particularly in confined or poorly ventilated spaces. White heavy- bodied gritty non- combustible high build texture coating with a mild ammonia odour. Miscible with water. PHYSICAL PROPERTIES
Lower Explosive Limit (%): Not applicable Upper Explosive Limit (%): Not applicable Decomposition Temp (ºC): Not available. Section 10 - CHEMICAL STABILITY AND REACTIVITY INFORMATION
CONDITIONS CONTRIBUTING TO INSTABILITY
· Hazardous polymerisation wil not occur. Section 11 - TOXICOLOGICAL INFORMATION
POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS
SWALLOWED
Considered an unlikely route of entry in commercial/industrial environments. The material is. discomforting to the gastro-intestinal tract if swal owed. EYE The liquid is discomforting to the eyes and is capable of causing a mild, temporary
redness of the conjunctiva (similar to wind-burn), temporary impairment of vision and/ or The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. SKIN The material is. mildly discomforting to the skin and is capable of causing skin
reactions which may lead to dermatitis from repeated exposures over long periods. The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swel ing, the production of vesicles, scaling and The vapour is mildly discomforting to the upper respiratory tract and lungs. Inhalation of vapour is more likely at higher than normal temperatures. The mist is. discomforting to the upper respiratory tract. CHRONIC HEALTH EFFECTS
Principal routes of exposure are usual y by. with the material and inhalation of vapour. Prolonged or repeated skin contact may cause drying with cracking, irritation and TOXICITY AND IRRITATION
Not available. Refer to individual constituents. No significant acute toxicological data identified in literature search. file://T:\Lab\WPDOCS\ADMNASST\Product Information\MSDS's Updated\Updates . 11/01/2008 unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances. The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swel ing, the production of vesicles, scaling and No evidence of carcinogenic properties. No evidence of mutagenic or unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances. Inhalation (human) TCLo: 16 mppcf*/8H/17.9Y WARNING: For inhalation exposure ONLY: This substance has been classified by the IARC as * Mil ions of particles per cubic foot (based on impinger samples counted NOTE : the physical nature of quartz in the product determines whether it is likely to present a chronic health problem. To be a hazard the material must enter the breathing zone as respirable particles. unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances. Inhalation (rat) LC50: >0.139 mg/l/14h * * [Grace] The substance is classified by IARC as Group 3: NOT classifiable as to its carcinogenicity to humans. Evidence of carcinogenicity may be inadequate or limited in animal testing. Reports indicate high/prolonged exposures to amorphous silicas induced lung fibrosis in experimental animals; in some experiments these effects were unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances. The material may produce moderate eye irritation leading to inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swel ing, the production of vesicles, scaling and unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances. The material may produce severe irritation to the eye causing pronounced inflammation. Repeated or prolonged exposure to irritants may produce conjunctivitis. file://T:\Lab\WPDOCS\ADMNASST\Product Information\MSDS's Updated\Updates . 11/01/2008 Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-al ergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur fol owing exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to severe bronchial hyperreactivity on methacholine chal enge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have also been included in the criteria for diagnosis of RADS. RADS (or asthma) fol owing an irritating inhalation is an infrequent disorder with rates related to the concentration of and duration of exposure to the irritating substance. Industrial bronchitis, on the other hand, is a disorder that occurs as result of exposure due to high concentrations of irritating substance (often particulate in nature) and is completely reversible after exposure ceases. The disorder is characterised by dyspnea, cough and mucus production. u nless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances. No significant acute toxicological data identified in literature search. unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances. The material may cause skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swel ing, the production of vesicles, scaling and WARNING: This substance has been classified by the IARC as Group 2B: Possibly Inhalation(human)LCLo: 10000 ppm/30m. Skin (rabbit): 500 mg - mild Inhalation (rat): 24000 mg/m³/4h Eye (rabbit): 100 mg/24h - moderate IARC: International Agency for Research on Cancer (IARC) Carcinogens: silica IARC: International Agency for Research on Cancer (IARC) Carcinogens: silica amorphous IARC: International Agency for Research on Cancer (IARC) Carcinogens: titanium dioxide IARC: International Agency for Research on Cancer (IARC) Carcinogens: styrene Category: Section 12 - ECOLOGICAL INFORMATION
No data for Wattyl Granosite Granotrowl. Refer to data for ingredients, which fol ows: file://T:\Lab\WPDOCS\ADMNASST\Product Information\MSDS's Updated\Updates . 11/01/2008 DO NOT discharge into sewer or waterways. DO NOT discharge into sewer or waterways. Aquatic toxicity (Daphnia magna) 24h EC50: >1000 mg/l Fish toxicity (Brachydanio rerio) 96h LC50: >10,000 mg/l [Grace] DO NOT discharge into sewer or waterways. In air ammonia is persistent whilst, in water, it biodegrades rapidly to nitrate, producing a high oxygen demand. Ammonia is strongly adsorbed to soil. Ammonia is non -persistent in water (half-life 2 days) and is moderately toxic to fish under normal temperature and pH conditions. Ammonia is harmful to aquatic life at low concentrations but does not concentrate in the food chain. Prevent, by any means available, spil age from entering drains or water Do NOT al ow product to come in contact with surface waters or to intertidal areas below the mean high water mark. Do not contaminate water when cleaning equipment or disposing Wastes resulting from use of the product must be disposed of on site or at approved waste DO NOT discharge into sewer or waterways. Half- life Surface water - High (hours): 672 Half- life Surface water - Low (hours): 336 Half- life Ground water - High (hours): 5040 Half- life Ground water - Low (hours): 672 Aqueous biodegradation - Aerobic - High (hours): 672 Aqueous biodegradation - Aerobic - Low (hours): 336 Aqueous biodegradation - Anaerobic - High (hours): 2688 Aqueous biodegradation - Anaerobic - Low (hours): 1344 Aqueous biodegradation - Removal secondary treatment - High (hours): 99% Aqueous biodegradation - Removal secondary treatment - Low (hours): 8% Photooxidation half- life air - High (hours): 7.3 Photooxidation half- life air - Low (hours): 0.9 Substances containing unsaturated carbons are ubiquitous in indoor environments. They result from many sources (see below). Most are reactive with environmental ozone and many produce stable products which are thought to adversely affect human health.The potential for surfaces in an enclosed space to facilitate reactions should be considered. file://T:\Lab\WPDOCS\ADMNASST\Product Information\MSDS's Updated\Updates . 11/01/2008 fol owing reaction with ozone.
Methacrolein, methyl vinyl Formaldehyde Formaldehyde, acetaldehyde, nicotinaldehyde, cotinineAcetone, geranyl acetone, file://T:\Lab\WPDOCS\ADMNASST\Product Information\MSDS's Updated\Updates . 11/01/2008 including ultrafine particlesFormaldehyde, 4-AMC, Abbreviations: 4-AMC, 4-acetyl-1-methylcyclohexene; 6MHQ, 6-methyl-5-heptene-2-one, 4OPA, 4-oxopentanal, SOA, Secondary Organic Aerosols Reference: Charles J Weschler; Environmental Helath Perspectives, Vol 114, October 2006. DO NOT discharge into sewer or waterways. Section 13 - DISPOSAL CONSIDERATIONS
· Recycle wherever possible or consult manufacturer for recycling options. · Consult State Land Waste Management Authority for disposal. · Bury residue in an authorised landfil . · Recycle containers if possible, or dispose of in an authorised landfil . Section 14 - TRANSPORTATION INFORMATION
NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS:UN, IATA, Section 15 - REGULATORY INFORMATION
POISONS SCHEDULE: None
REGULATIONS
Wattyl Granosite Granotrowl (CAS: None): calcium carbonate (CAS: 471-34-1) is found on the fol owing regulatory lists; Australia High Volume Industrial Chemical List (HVICL) Australia Inventory of Chemical Substances (AICS) Australia Therapeutic Goods Administration (TGA) Substances that may be used as active ingredients in Listed medicines CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP International Council of Chemical Associations (ICCA) - High Production Volume List OECD Representative List of High Production Volume (HPV) Chemicals calcium carbonate (CAS: 1317-65-3) is found on the fol owing regulatory lists; Australia Inventory of Chemical Substances (AICS) OECD Representative List of High Production Volume (HPV) Chemicals silica crystal ine - quartz (CAS: 14808-60-7) is found on the fol owing regulatory lists; Australia - New South Wales Hazardous Substances Prohibited for Specific Uses Australia - New South Wales Hazardous Substances Requiring Health Surveil ance Australia - South Australia Hazardous Substances Requiring Health Surveil ance file://T:\Lab\WPDOCS\ADMNASST\Product Information\MSDS's Updated\Updates . 11/01/2008 Australia - Tasmania Hazardous Substances Prohibited for Specified Uses Australia - Tasmania Hazardous Substances Requiring Health Surveil ance Australia - Western Australia Hazardous Substances Requiring Health Surveil ance Australia Hazardous Substances Requiring Health Surveil ance Australia High Volume Industrial Chemical List (HVICL) Australia Inventory of Chemical Substances (AICS) Australia Occupational Health and Safety (Commonwealth Employment) (National Standards) Regulations 1994 International Agency for Research on Cancer (IARC) Carcinogens OECD Representative List of High Production Volume (HPV) Chemicals silica amorphous (CAS: 7631-86-9) is found on the fol owing regulatory lists; Australia High Volume Industrial Chemical List (HVICL) Australia Inventory of Chemical Substances (AICS) Australia Therapeutic Goods Administration (TGA) Substances that may be used as active ingredients in Listed medicines CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP International Agency for Research on Cancer (IARC) Carcinogens International Council of Chemical Associations (ICCA) - High Production Volume List OECD Representative List of High Production Volume (HPV) Chemicals silica amorphous (CAS: 112945-52-5) is found on the fol owing regulatory lists; Australia High Volume Industrial Chemical List (HVICL) Australia Inventory of Chemical Substances (AICS) International Council of Chemical Associations (ICCA) - High Production Volume List OECD Representative List of High Production Volume (HPV) Chemicals titanium dioxide (CAS: 13463-67-7) is found on the fol owing regulatory lists; Australia High Volume Industrial Chemical List (HVICL) Australia Inventory of Chemical Substances (AICS) Australia Therapeutic Goods Administration (TGA) Substances that may be used as active ingredients in Listed medicines Australia Therapeutic Goods Administration (TGA) Sunscreening agents permitted as active ingredients in listed products CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP International Agency for Research on Cancer (IARC) Carcinogens OECD Representative List of High Production Volume (HPV) Chemicals titanium dioxide (CAS: 1317-70-0) is found on the fol owing regulatory lists; Australia Inventory of Chemical Substances (AICS) OECD Representative List of High Production Volume (HPV) Chemicals titanium dioxide (CAS: 1317-80-2) is found on the fol owing regulatory lists; Australia Inventory of Chemical Substances (AICS) OECD Representative List of High Production Volume (HPV) Chemicals ammonium hydroxide (CAS: 1336-21-6) is found on the fol owing regulatory lists; Australia - Australian Capital Territory - Environment Protection Regulation: Pol utants entering waterways taken to cause environmental harm (Aquatic Australia - Australian Capital Territory Environment Protection Regulation Pol utants entering waterways - Domestic water quality Australia - Queensland Hazardous Materials and Prescribed Quantities for Major Hazard Facilities Australia High Volume Industrial Chemical List (HVICL) Australia Inventory of Chemical Substances (AICS) Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2) Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix F (Part 3) Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5 Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 6 CODEX General Standard for Food Additives (GSFA) - Additives Permitted for Use in Food in General, Unless Otherwise Specified, in Accordance with GMP IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk International Council of Chemical Associations (ICCA) - High Production Volume List OECD Representative List of High Production Volume (HPV) Chemicals WHO Guidelines for Drinking-water Quality - Chemicals for which guideline values have not been established water (CAS: 7732-18-5) is found on the fol owing regulatory lists; Australia Inventory of Chemical Substances (AICS) Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2) Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix F (Part 3) file://T:\Lab\WPDOCS\ADMNASST\Product Information\MSDS's Updated\Updates . 11/01/2008 OECD Representative List of High Production Volume (HPV) Chemicals styrene (CAS: 100-42-5) is found on the fol owing regulatory lists; Australia - Australian Capital Territory - Environment Protection Regulation: Ambient environmental standards (Domestic water supply Australia - Australian Capital Territory Environment Protection Regulation Pol utants entering waterways - Domestic water quality Australia Dangerous Goods Code Draft 7th Edition - Goods too Dangerous to be Transported Australia High Volume Industrial Chemical List (HVICL) Australia Inventory of Chemical Substances (AICS) Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix E (Part 2) Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Appendix F (Part 3) Australia Standard for the Uniform Scheduling of Drugs and Poisons (SUSDP) - Schedule 5 IMO MARPOL 73/78 (Annex II) - List of Noxious Liquid Substances Carried in Bulk International Agency for Research on Cancer (IARC) Carcinogens International Air Transport Association (IATA) Dangerous Goods Regulations OECD Representative List of High Production Volume (HPV) Chemicals WHO Guidelines for Drinking-water Quality - Guideline values for chemicals that are of health significance in drinking No data available for acrylic copolymer latex as CAS: Not avail. No data available for calcium carbonate as CAS: 13397-26-7, CAS: 15634-14-7. No data available for titanium dioxide as CAS: 12188-41-9. Section 16 - OTHER INFORMATION
INGREDIENTS WITH MULTIPLE CAS NUMBERS
471-34-1, 13397-26-7, 15634-14-7, 1317-65-3 13463-67-7, 1317-70-0, 1317-80-2, 12188-41-9 REPRODUCTIVE HEALTH GUIDELINES
Established occupational exposure limits frequently do not take into consideration reproductive end points that are clearly below the thresholds for other toxic effects. Occupational reproductive guidelines (ORGs) have been suggested as an additional standard. These have been established after a literature search for reproductive no -observed-adverse effect-level (NOAEL) and the lowest-observed-adverse-effect-level (LOAEL). In addition the US EPA's procedures for risk assessment for hazard identification and dose-response assessment as applied by NIOSH were used in the creation of such limits. Uncertainty factors (UFs) have also been incorporated. These exposure guidelines have been derived from a screening level of risk assessment and should not be construed as unequivocal y safe limits. ORGS represent an 8-hour time -weighted average unless specified otherwise. CR = Cancer Risk/10000; UF = Uncertainty factor: TLV believed to be adequate to protect reproductive health: Toxic endpoints have also been identified as: D = Developmental; R = Reproductive; TC = Transplacental carcinogen Jankovic J., Drake F.: A Screening Method for Occupational Reproductive American Industrial Hygiene Association Journal 57: 641-649 (1996). Classification of the preparation and its individual components has drawn on official and authoritative sources as wel as independent review by the Chemwatch Classification committee using available literature references.
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from CHEMWATCH. TEL (+61 3) 9572 4700.
file://T:\Lab\WPDOCS\ADMNASST\Product Information\MSDS's Updated\Updates . 11/01/2008 file://T:\Lab\WPDOCS\ADMNASST\Product Information\MSDS's Updated\Updates . 11/01/2008

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