Material Safety Data Sheet Lithium Thionylchloride (Li/SOCl2) non-rechargeable batteries 1. IDENTIFICATION PRODUCT NAME: DYNAMIS LITHIUM-LINE, Lithium Thionyl Chloride Cells and Batteries CHEMICAL REACTION: 4Li + 2S0Cl2 -> 4LiCI + S + SO2 HAZARDOUS INGREDIENTS: NAME CAS # OSHA/NIOSH/ACGIH
2. PHYSICAL DATA BOILING POINT: N/A
If forced open, the ingredients hydrolyze to form SO2, HCI, LiOH
3. FIRE AND EXPLOSION HAZARD DATA FLASH POINT:
Lith-X or other metal fire extinguisher powder (Class D).
Do not use water, sand, carbon dioxide or soda ash
extinguisher. Use water protective breathing apparatus and protective garments.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Do not short circuit, recharge, overdischarge, puncture,
incinerate, crush or expose to temperature above the temperature rating of the battery.
DYNAMIS Batterien GmbH Brühl 15 78465 Dettingen/Konstanz – Germany Tel. +49 (0) 7533/93669-0 Fax +49 (0) 7533/93669-91 [email protected] 4. REACTIVITY DATA STABILlTY: Stable CONDITIONS TO AVOID:
Fire, heat over the temperature rating of the battery, electrical shorting, recharging, disassembly. Refer to our DYNAMIS material safety data sheet for safe handling information (shipped with product).
Do not expose internal components to water.
HAZARDOUS DECOMPOSITION PRODUCTS: SO2, HCI, LiOH and H2 HAZARDOUS POLYMERIZATION :
5. HEALTH HAZARD DATA ROUTES OF ENTRY : INHALATION: NO INGESTION: NO SKIN: NO (Under normal conditions) HEALTH HAZARD :
None, unless battery ruptures. In the event of exposure to
internal contents, corrosive fumes will be very irritating to skin, eyes and mucous membranes. Overexposure can cause symptoms of non-fibrotic lung injury and membrane irritation.
MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE:
In the event of exposure to internal contents, eczema, skin allergies, lung injuries, asthma and other respiratory disorders may occur.
EMERGENCY FIRST AID PROCEDURES : Eye Contact:
Flush with running water for at least 15 minutes. Hold eyelids apart. Seek immediate medical treatment.
Remove particles of Lithium from skin as fast as possible. Rinse with large amounts of running water for at least 15 min. If burns develop seek medical treatment.
Remove to fresh air. Seek for medical attention. With large quantities and irritation of the respiratory tract, stay under medical surveillance for 48 hours. Immediately inhale Cortisone spray, e.g. Pulmicort.
Remove to fresh air, provide Oxygen and seek medical treatment. Seek immediate medical treatment.
DYNAMIS Batterien GmbH Brühl 15 78465 Dettingen/Konstanz – Germany Tel. +49 (0) 7533/93669-0 Fax +49 (0) 7533/93669-91 [email protected] 6. PRECAUTIONS FOR SAFE HANDLING AND USE
STEPS TO BE TAKEN IF MATERIAL IS SPILLED OR RELEASED:
Do not breathe vapors or touch liquid with bare hands.
Neutralize spill with soda lime, seal leaking battery and soda lime in plastic bag and dispose of as hazardous waste.
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
Do not short circuit or expose to temperatures above the temperature rating of the battery. Do not recharge.
OTHER PRECAUTIONS AND/OR SPECIAL HAZARDS :
Do not store batteries in high humidity environments for long periods. High temperature storage will degrade performance. Refer to our DYNAMIS material safety data sheet for safe handling information (shipped with product).
7. CONTROL MEASURES RESPIRATORY PROTECTION:
As in any fire or chemical spill situation, use self-contained breathing apparatus if a cell vents or fire occurs.
Safety glasses are recommended during handling of any lithium cell or battery.
In the event of leakage, wear chemical apron.
LOCAL EXHAUST: Recommended in a vent or leak situation.
OTHER: N/A 8. TRANSPORTATION
CLASS 9 UN3090: Lithium
Lithium batteries contained in equipment or
SPECIAL PROVISIONS AND PACKING INSTRUCTIONS: ADR, RID:
DYNAMIS Batterien GmbH Brühl 15 78465 Dettingen/Konstanz – Germany Tel. +49 (0) 7533/93669-0 Fax +49 (0) 7533/93669-91 [email protected]
9. REGULATORY INFORMATION
OSHA Status: The internal component (thionyl chloride) is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1920.1200. Shipping Requirements: The cell and batteries are subject to the shipping requirement and exceptions under 49 CFR 173.185. The cells with a lithium content of greater than 0.5 grams and less than 12 grams are restricted, and they are subject to DOT (49 CFR) and IATA shipping regulations. Cells that contain less than 0.5 grams of lithium and batteries that contain less than 1.0 grams of lithium are unrestricted, and they can be shipped by any means [49 CFR 173.185 (a)(c)]. DYNAMIS Batterien GmbH Brühl 15 78465 Dettingen/Konstanz – Germany Tel. +49 (0) 7533/93669-0 Fax +49 (0) 7533/93669-91 [email protected]
Christine A. Papa, D.O. Professional Experience 07/2000 to Present Macaione and Papa Dermatology Associates, PA President, Board Certified Dermatologist, Mohs Micrographic Surgeon Postgraduate Training Penn State Geisinger Health System Geisinger Medical Center, Danville, PA Mohs Micrographic Surgery and Cutaneous Oncology Fellowship University of Medicine & De
Idaho Educational Services for the Deaf and the Blind Serving the Deaf and the Blind Students of Idaho Since 1906 OVER-THE-COUNTER HOUSE MEDICATIONS POLICY The following are the medications that have been approved for ISDB use by our school physician. We will use only these medications until we receive medications from parents/guardians. Bee sting allergy medication: Epinephrine. Lic