SAFETY DATA SHEET Compilation date: 24/07/2007 Revision date: 24/02/2012 Revision No: 9 Section 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product name: HRED/L HARDENER BPO Product code: HRED/L 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of substance / mixture: HARDENER CONTAINING BENZOYL PEROXIDE 1.3. Details of the supplier of the safety data sheet Company name: U-POL Limited Tel: +44-(0)-1933 230300 Fax: +44-(0)-1933 425797 1.4. Emergency telephone number Emergency tel: +44-(0)-1933 230310 Section 2: Hazards identification 2.1. Classification of the substance or mixture Classification under CHIP: Xi: R36; Sens.: R43; -: R52/53; O: R7 Most important adverse effects: Irritating to eyes. May cause sensitisation by skin contact. Harmful to aquatic organisms,
may cause long-term adverse effects in the aquatic environment. May cause fire.
Classification under CLP: This product has no classification under CLP. 2.2. Label elements Label elements under CHIP: Hazard symbols: Irritant. Risk phrases: R36: Irritating to eyes. SAFETY DATA SHEET
R43: May cause sensitisation by skin contact.
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the
Safety phrases: S24: Avoid contact with skin.
S3/7: Keep container tightly closed in a cool place.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek
S36/37/39: Wear suitable protective clothing, gloves and eye / face protection. 2.3. Other hazards PBT: This substance is not identified as a PBT substance. Section 3: Composition/information on ingredients 3.2. Mixtures Hazardous ingredients: Section 4: First aid measures 4.1. Description of first aid measures Skin contact: Wash immediately with plenty of soap and water. Remove all contaminated clothes and
footwear immediately unless stuck to skin.
Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist Ingestion: Do not induce vomiting. Wash out mouth with water. Transfer to hospital as soon as 4.2. Most important symptoms and effects, both acute and delayed Skin contact: There may be irritation and redness at the site of contact. Eye contact: There may be irritation and pain. Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach Inhalation: No symptoms. Delayed / immediate effects: Immediate effects can be expected after short-term exposure. SAFETY DATA SHEET 4.3. Indication of any immediate medical attention and special treatment needed Immediate / special treatment: Eye bathing equipment should be available on the premises. Section 5: Fire-fighting measures 5.1. Extinguishing media Extinguishing media: Carbon dioxide. Dry chemical powder. Alcohol or polymer foam. 5.2. Special hazards arising from the substance or mixture Exposure hazards: In combustion emits toxic fumes of carbon dioxide / carbon monoxide. Oxidising. 5.3. Advice for fire-fighters Advice for fire-fighters: Wear self-contained breathing apparatus. Section 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures Personal precautions: Refer to section 8 of SDS for personal protection details. 6.2. Environmental precautions Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding. 6.3. Methods and material for containment and cleaning up Clean-up procedures: Absorb into dry earth or sand. Wash the spillage site with large amounts of water. 6.4. Reference to other sections Reference to other sections: Refer to section 8 of SDS. Section 7: Handling and storage 7.1. Precautions for safe handling Handling requirements: Ensure there is sufficient ventilation of the area. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions: Store in cool, well ventilated area. Keep away from sources of ignition. Keep container Suitable packaging: Must only be kept in original packaging. 7.3. Specific end use(s) Specific end use(s): No data available. Section 8: Exposure controls/personal protection 8.1. Control parameters SAFETY DATA SHEET Workplace exposure limits: Respirable dust Hazardous ingredients: DIBENZOYL PEROXIDE Workplace exposure limits: Respirable dust 8.2. Exposure controls Engineering measures: Ensure there is sufficient ventilation of the area. Respiratory protection: Respiratory protection not required. Hand protection: Nitrile gloves. Eye protection: Safety goggles. Ensure eye bath is to hand. Skin protection: Protective clothing. Rubber apron. Section 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties State: Paste Colour: Red Odour: Barely perceptible odour Evaporation rate: Negligible Oxidising: Oxidising (by EC criteria) Solubility in water: Insoluble Viscosity: Viscous Kinematic viscosity: 1000cps Autoflammability°C: >380 Relative density: 1.2 VOC g/l: 274 9.2. Other information Other information: Not applicable. Section 10: Stability and reactivity 10.1. Reactivity Reactivity: Stable under recommended transport or storage conditions. 10.2. Chemical stability Chemical stability: Stable under normal conditions. SADT (Self-Accelerating Decomposition Temperature) SAFETY DATA SHEET 10.3. Possibility of hazardous reactions Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.
Decomposition may occur on exposure to conditions or materials listed below.
10.4. Conditions to avoid Conditions to avoid: Direct sunlight. Heat. Hot surfaces. Sources of ignition. 10.5. Incompatible materials Materials to avoid: Reducing agents. Acids. Bases. Metals. 10.6. Hazardous decomposition products Haz. decomp. products: In combustion emits toxic fumes. Section 11: Toxicological information 11.1. Information on toxicological effects Relevant effects for mixture: Symptoms / routes of exposure Skin contact: There may be irritation and redness at the site of contact. Eye contact: There may be irritation and pain. Ingestion: There may be soreness and redness of the mouth and throat. Nausea and stomach Inhalation: No symptoms. Delayed / immediate effects: Immediate effects can be expected after short-term exposure. Section 12: Ecological information 12.1. Toxicity Ecotoxicity values: Not applicable. 12.2. Persistence and degradability Persistence and degradability: Biodegradable. 12.3. Bioaccumulative potential Bioaccumulative potential: No data available. 12.4. Mobility in soil Mobility: Insoluble in water. SAFETY DATA SHEET 12.5. Results of PBT and vPvB assessment PBT identification: This substance is not identified as a PBT substance. 12.6. Other adverse effects Other adverse effects: Harmful to aquatic organisms. Section 13: Disposal considerations 13.1. Waste treatment methods Disposal operations: Incineration on land. Disposal of packaging: Dispose of in a regulated landfill site or other method for hazardous or toxic wastes. NB: The user's attention is drawn to the possible existence of regional or national Section 14: Transport information 14.1. UN number UN number: UN3108 14.2. UN proper shipping name Shipping name: ORGANIC PEROXIDE, TYPE E, SOLID 14.3. Transport hazard class(es) Transport class: 5.2 14.4. Packing group 14.5. Environmental hazards Environmentally hazardous: No Marine pollutant: No 14.6. Special precautions for user Special precautions: No special precautions. Tunnel code: D Transport category: 2 Section 15: Regulatory information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture 15.2. Chemical Safety Assessment Chemical safety assessment: A chemical safety assessment has not been carried out for the substance or the mixture Section 16: Other information Other information Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No SAFETY DATA SHEET
FOR PROFESSIONAL USE ONLY. Read full instructions before use.
IMPORTANT: This product contains hazardous materials and therefore appropriate
personal protective equipment should always be used.
Please refer to the label and consult the material safety data sheet for full handling
instructions and personal protection information. These are available via your local
stockist or via the U-POL website at .
U-POL disclaim any liability where the user does not wear the recommended personal
Phrases used in s.2 and 3: H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
R3: Extreme risk of explosion by shock, friction, fire or other sources of ignition.
R43: May cause sensitisation by skin contact.
R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the
Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive
and shall be used only as a guide. Addition of reducers, hardeners and other additives
over and above U-POL's recommendations for use, may substantially alter the
composition and hazards of the product. Since conditions of use are outside our control,
this company shall not be held liable for any damage resulting from handling or from
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Northern Valley Dairy Production Medicine Center 900 N Wabasha, Plainview, MN 55964 (507) 534-4356, 1-888-534-4026 Dehorning and castration are necessary procedures in the cattle business. We all know that cattle have to be dehorned to protect animal and workers. We also know markets demand meat from steers, and that young bulls can be dangerous to humans. Our industry is coming under more a
SAFETY DATA SHEET